Thermionic emission is the liberation of electrons from an electrode by virtue of its temperature (releasing of energy supplied by heat). This occurs because the thermal energy given to the charge carrier overcomes the work function of the material. The charge carriers can be electrons or ions, and in older literature are sometimes referred to as thermions. After emission, a charge that is equal in magnitude and opposite in sign to the total charge emitted is initially left behind in the emitting region. But if the emitter is connected to a battery, the charge left behind is neutralized by charge supplied by the battery as the emitted charge carriers move away from the emitter, and finally the emitter will be in the same state as it was before emission.

The classical example of thermionic emission is that of electrons from a hot cathode into a vacuum (also known as thermal electron emission or the Edison effect) in a vacuum tube. The hot cathode can be a metal filament, a coated metal filament, or a separate structure of metal or carbides or borides of transition metals. Vacuum emission from metals tends to become significant only for temperatures over 1,000 K (730 C; 1,340 F).

This process is crucially important in the operation of a variety of electronic devices and can be used for electricity generation (such as thermionic converters and electrodynamic tethers) or cooling. The magnitude of the charge flow increases dramatically with increasing temperature.

The term 'thermionic emission' is now also used to refer to any thermally-excited charge emission process, even when the charge is emitted from one solid-state region into another.

Thomas Alva Edison (February 11, 1847 – October 18, 1931) was an American inventor and businessman. He developed many devices in fields such as electric power generation, mass communication, sound recording, and motion pictures. These inventions, which include the phonograph, the motion picture camera, and early versions of the electric light bulb, have had a widespread impact on the modern industrialized world. He was one of the first inventors to apply the principles of organized science and teamwork to the process of invention, working with many researchers and employees. He established the first industrial research laboratory.Edison was raised in the American Midwest; early in his career, he worked as a telegraph operator, which inspired some of his earliest inventions. In 1876, he established his first laboratory facility in Menlo Park, New Jersey, where many of his early inventions were developed. He later established a botanical laboratory in Fort Myers, Florida, in collaboration with businessmen Henry Ford and Harvey S. Firestone, and a laboratory in West Orange, New Jersey, that featured the world's first film studio, the Black Maria. He was a prolific inventor, holding 1,093 US patents in his name, as well as patents in other countries. Edison married twice and fathered six children. He died in 1931 of complications of diabetes.