Neptune is the eighth and farthest-known Solar planet from the Sun. In the Solar System, it is the fourth-largest planet by diameter, the third-most-massive planet, and the densest giant planet. It is 17 times the mass of Earth, and slightly more massive than its near-twin Uranus. Neptune is denser and physically smaller than Uranus because its greater mass causes more gravitational compression of its atmosphere. It is referred to as one of the solar system's two ice giant planets (the other one being its Uranus).

Being composed primarily of gases and liquids, it has no well-defined "solid surface". The planet orbits the Sun once every 164.8 years at an average distance of 30.1 AU (4.5 billion km; 2.8 billion mi). It is named after the Roman god of the sea and has the astronomical symbol , representing Neptune's trident.Neptune is not visible to the unaided eye and is the only planet in the Solar System found by mathematical prediction rather than by empirical observation. Unexpected changes in the orbit of Uranus led Alexis Bouvard to hypothesise that its orbit was subject to gravitational perturbation by an unknown planet. After Bouvard's death, the position of Neptune was predicted from his observations, independently, by John Couch Adams and Urbain Le Verrier. Neptune was subsequently observed with a telescope on 23 September 1846 by Johann Galle within a degree of the position predicted by Le Verrier. Its largest moon, Triton, was discovered shortly thereafter, though none of the planet's remaining 13 known moons were located telescopically until the 20th century. The planet's distance from Earth gives it a very small apparent size, making it challenging to study with Earth-based telescopes. Neptune was visited by Voyager 2, when it flew by the planet on 25 August 1989; Voyager 2 remains the only spacecraft to have visited Neptune. The advent of the Hubble Space Telescope and large ground-based telescopes with adaptive optics has recently allowed for additional detailed observations from afar.

Like Jupiter and Saturn, Neptune's atmosphere is composed primarily of hydrogen and helium, along with traces of hydrocarbons and possibly nitrogen, though it contains a higher proportion of "ices" such as water, ammonia and methane. However, similar to Uranus, its interior is primarily composed of ices and rock; Uranus and Neptune are normally considered "ice giants" to emphasise this distinction. Traces of methane in the outermost regions in part account for the planet's blue appearance, though an unknown component is believed to color Neptune a deeper blue compared to Uranus.In contrast to the hazy, relatively featureless atmosphere of Uranus, Neptune's atmosphere has active and visible weather patterns. For example, at the time of the Voyager 2 flyby in 1989, the planet's southern hemisphere had a Great Dark Spot comparable to the Great Red Spot on Jupiter. More recently, in 2018, a newer main dark spot and smaller dark spot were identified and studied. In addition, these weather patterns are driven by the strongest sustained winds of any planet in the Solar System, with recorded wind speeds as high as 2,100 km/h (580 m/s; 1,300 mph). Because of its great distance from the Sun, Neptune's outer atmosphere is one of the coldest places in the Solar System, with temperatures at its cloud tops approaching 55 K (218 C; 361 F). Temperatures at the planet's centre are approximately 5,400 K (5,100 C; 9,300 F). Neptune has a faint and fragmented ring system (labelled "arcs"), which was discovered in 1984, then later confirmed by Voyager 2.

Pluto (minor-planet designation: 134340 Pluto) is a dwarf planet in the Kuiper belt, a ring of bodies beyond the orbit of Neptune. It was the first object to be discovered in the Kuiper belt, and remains the largest known body in that area.

After Pluto was discovered in 1930, it was declared to be the ninth planet from the Sun. Beginning in the 1990s, its status as a planet was questioned following the discovery of several objects of similar size in the Kuiper belt and the scattered disc, including the dwarf planet Eris. This led the International Astronomical Union (IAU) in 2006 to formally define the term planet—excluding Pluto and reclassifying it as a dwarf planet.

Pluto is the ninth-largest and tenth-most-massive known object directly orbiting the Sun. It is the largest known trans-Neptunian object by volume but is less massive than Eris. Like other Kuiper belt objects, Pluto is primarily made of ice and rock and is relatively small—one-sixth the mass of the Moon and one-third its volume. It has a moderately eccentric and inclined orbit during which it ranges from 30 to 49 astronomical units or AU (4.4–7.4 billion km) from the Sun. This means that Pluto periodically comes closer to the Sun than Neptune, but a stable orbital resonance with Neptune prevents them from colliding. Light from the Sun takes 5.5 hours to reach Pluto at its average distance (39.5 AU).

Pluto has five known moons: Charon (the largest, with a diameter just over half that of Pluto), Styx, Nix, Kerberos, and Hydra. Pluto and Charon are sometimes considered a binary system because the barycenter of their orbits does not lie within either body.

The New Horizons spacecraft performed a flyby of Pluto on July 14, 2015, becoming the first and, to date, only spacecraft to do so. During its brief flyby, New Horizons made detailed measurements and observations of Pluto and its moons. In September 2016, astronomers announced that the reddish-brown cap of the north pole of Charon is composed of tholins, organic macromolecules that may be ingredients for the emergence of life, and produced from methane, nitrogen and other gases released from the atmosphere of Pluto and transferred 19,000 km (12,000 mi) to the orbiting moon.